Though the GearVR works with Samsung Galaxy S6 and S6 Edge make sure the phone you have is in a region that can download the GearVR app otherwise you will need to check the model of your phone and flash rom to a region that does. Developing in unsupported countries is a pain in the ass. Next time buying both phone and GearVR from same location.
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Pro Tip: Gear Vr
Managing the Game 